Consider the elements fluorine, calcium, and argon. The element with the most negative electron affinity is....
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X(g) + e^- ---------------> X^- (g) H= - ve
Fluorine valence shell contains 7 electrons. Fluorine gain one electron to get nearer inert gas electron configuration (neon). Fluorine easly gain electrons. so more amount of energy is released.
F(g) + e^- --------------> F^- (g) H= - 328KJ
calcium valence shell contains 2 electrons.It has stable electron configuration because of S-orbital completely filled.Calcium not easly gain electrons.
Argon has stable electron configuration in it's valence shell. So it is not gain electron .Argon electron afffinity is zero.
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