Acid is initially having low pH value (Depending upon the strength of acid).
Alka Seltzer is an alkaline component.
There will occur a neutralization reaction between acid and Alka Seltzer.
Alka Seltzer is a basic compound with excess HO- ions and hence pOH less than 7.
Progressive addition of acid to alka seltzer consumes HO- ions and lowers down concentration.
As pOH = - log[HO-] = log(1/[HO-]) with decrease in [HO-], pOH increases.
Hence on addition of acid to Alka Seltzer pOH increases. and pH decreases.
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