Question

explain why cyano or phosphine ligands are place high in the spectrochemical series but the hydroxide...

explain why cyano or phosphine ligands are place high in the spectrochemical series but the hydroxide ligand or the halo ligands are quite low in the spectrochemical series?

Homework Answers

Answer #1

Ligands that produce a small splitting are called weak-field ligands and lie at the left end of the series. Ligands that produce a large splitting are called strong-field ligands and lie at the right end of the series.

It is based on sigma and pi bonding interaction. Also size of ligands play a role. Smaller the size, more closer will be ligand to the central atom and hence greater splitting.

It is a big process which is nicely explained in below link:
http://www.chm.davidson.edu/vce/coordchem/Ligands.html

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