The process of heating to make a substance saturated vapor is done during phase change from liquid state to vapor state. In this case, the R-134a is at a higher pressure (as its normal boiling point is ~- 26-degree celsius). Thus, it undergoes a phase change in the given process, and phase change typically happens at a constant temperature. But the vessel here is also given to be rigid. Hence the most appropriate option to be chose would be Option c: constant volume because the rigidity of the container cannot be violated at any cost.
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