Question

What is the ideal solvent for crystallization if a particular compound?

What is the ideal solvent for crystallization if a particular compound?

Homework Answers

Answer #1

The ideal recrystallization solvent should possess the following characteristics:

  • The compound of interest should fully dissolve in hot (boiling) solvent.
  • The compound of interest should have little or no solubility in the solvent at room temperature.
  • The boiling point of the solvent should be lower than the melting point of the compound of interest. If it is not, you may obtain an oil rather than crystals.
  • The solvent should have a fairly low boiling point (this makes it easier to remove by evaporation when air drying). Also allows you to use a low temperature oven to remove any traces of solvent.
  • The solvent should be inexpensive, non-toxic, non reactive, and have a low odor.
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