Question

A specific example (reactant, reagent, product) of a 4 electron oxidation.

A specific example (reactant, reagent, product) of a 4 electron oxidation.

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Answer #1

Four-electron oxidation of the quadruply bonded W2(II,II) compound W2(2,2′-dipyridylamide)4  results in the formation of a novel, diamagnetic ditungsten terminal oxo compound [W2O(2,2′-dipyridylamide)4]2+.

Chemically Reversible Four-Electron Oxidation and Reduction Utilizing Two Inorganic Functional Groups

Michael Nippe, Samuel M. Goodman, Charles G. Fry, and John F. Berry

Journal of the American Chemical Society 2011 133 (9), 2856-2859

DOI: 10.1021/ja1114248

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