For the reaction given below, 2.00 moles of A and 3.00 moles of B are placed in a 6.00-L container. A(g) + 2B(g) C(g) At equilibrium, the concentration of A is 0.220 mol/L. What is the value of K? (6.90)
[A] = 2 mol / 6 L = 0.333 M
[B] = 3 mol/ 6 L = 0.5 M
A(g) + 2B(g) <-------------> C(g)
Initial 0.333 M 0.5 M 0
at equilibrium 0.333 -x 0.5-2x x
Hence,
equilibrium concentration of A = 0.333 -x
But given that equilibrium concentration of A = 0.220 M
Then, 0.333 -x = 0.22
x = 0.113 M
Therefore,
equilibrium concentrations are
[A] = 0.22 M
[B] = 0.5 - 2 x =0.5 - 2(0.113) = 0.274 M
[C] = x = 0.113 M
Then,
K = [C]/ [A] [B]2
= 0.113 / (0.22) (0.274)2
= 6.9
Therefore,
K = 6.90
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