100. What mass (in g) of silver can be electroplated when 0.406 amps are used for 1.011 hours using a solution of silver nitrate?
Electrolysis equation is:
Ag1+ + 1e- ------>
Ag
1 mol of Ag requires 1 mol of electron
1 mol of electron = 96485 C
So,1 mol of Ag requires 96485 C
let us calculate the charge passed:
t = 1.011 hr = 1.011*3600 s = 3639 s
time, t = 3639s
Q = I*t
= 0.406A * 3639s
= 1477.434 C
mol of Ag plated = 1477.434/96485 = 0.01531 mol
Molar mass of Ag = 107.9 g/mol
mass of Ag = number of mol * molar mass
= 0.01531 * 107.9
= 1.65 g
Answer: 1.65 g
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