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What is the maximum number of formula isomers possible when methane is chlorinated by the free-radical...

What is the maximum number of formula isomers possible when methane is
chlorinated by the free-radical mechanism?

1

2

3

4
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Answer #1

Substitution reaction occur when hydrogen atoms in the methane are replaced one at a time by chlorine atoms via free radical mechanism.

At the end of the reaction a mixture of chloromethane, dichloromethane ,trichloromethane and tetrachloromethane.

CH4 + Cl2 ---> CH3Cl + HCl

CH3Cl + Cl2 ---> CH2Cl2 + HCl

CH2Cl2 + Cl2 ---> CHCl3+ HCl

CHCl3 + Cl2 ---> CCl4+ HCl

So the maximum number of formula isomers possible when methane is chlorinated by the free-radical mechanism are 4

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