Use the synthesis of methanol to answer the quesCons
below.
CO(g) + 2H2(g) ? CH3OH(g) ΔHrxn = –90.8 kcal; Kc = 10.5 at
500˚C
a. (3 pts) Write the rate law for the forward reacCon. Assume this
is an elementary
reacCon.
rate = ______________________
b. (3 pts) Write the rate law for the reverse reacCon. Assume this
is an elementary
reacCon.
rate = ______________________
c. (3 pts) By staCng that a chemical reacCon is “elementary”, which
one assumpCon is
made about the relaConship between the reacCon and its rate
law?
i. The reacCon involves mulCple separate collisions of the starCng
materials.
ii. The stoichiometry (moles) of each reactant matches its rate
order.
iii. The reacCon involves only elements, not compounds.
iv. A elementary reacCon is one that Holmes understands, but Watson
doesn’t.
d. (6 pts) At a given Cme in the reacCon, [CH3OH] = 0.50 M, [CO] =
0.25 M, and [H2] =
0.15 M. Calculate the reacCon quoCent (Q) at this point in the
reacCon.
e. (3 pts) True or False? Based on the value of Q calculated in
ques@on 1d, the reacCon
will shik to make more products in order to reach
equilibrium._______
f. (6 pts) Using Le Châtelier’s Principle, briefly describe two
ways (using pressure,
temperature, and/or concentraCon changes) in which this equilibrium
could be shiked
to make more methanol (CH3OH).
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