Question

in what direction are the ions in NaCl and CsCl touching based on the unit cell?...

in what direction are the ions in NaCl and CsCl touching based on the unit cell? (edge, face diagonal or body diagonal)

Homework Answers

Answer #1

NaCl has a cubic unit cell. It is face-centered cubic array of anions with an interpenetrating fcc cation lattice (or vice-versa). The cell looks the same whether you start with anions or cations on the corners.

Each ion is 6-coordinate and has a local octahedral geometry

The structure can be described as: The cesium ions from the simple cubic arrangement. Chloride ions occupy the cubic interstitial sites, i.e., each chloride ion has eight cesium ions as its nearest neighbours.

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