An ancient scroll allegedly originates from Greek scholars in about 500 B.C. A measure of its carbon -14 decay rate gives a value that is 89% of that found in living organisms. How old is the scroll and could it be authentic?
We know that
half life of carbon-14, t1/2 = 5730 yrs
Radio active decay is a first order reaction.
For first order recation,
half life t1/2 = 0.693 /k where k is rate constant
k = 0.693/ t1/2 --- Eq (1)
k = 1/t ln { [A]o/[A]t} -----Eq (2)
From Eqs (1) and (2),
0.693/ t1/2 = (1/t) ln {[A]o/ [A]t} ------Eq (3)
t1/2 = 5730 yrs
t = age of the object
Given that [A]t = 89 % of the carbon-14
[A]o = 100 % of the carbon-14
Substitute all the values in Eq (3),
0.693/ t1/2 = (1/t) ln {[A]o/ [A]t}
0.693/ 5730 yrs = (1/t) In (100/89)
t = In (100/89) x 5730 yrs / 0.693
= 963.5 yrs
t = 963.5 yrs
Therefore, age of scroll = 963.5 yrs
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