Assuming DIPEA (N,N- diisopropylethylamine) is dissolved in water, write an approximately pH value where:
a. Exactly half of the molecules of DIPEA are protonated (half deprotonated)
b. The ratio of protonated to deprotonated molecules is 100:1 (100 protonated, 1 deprotonated)
c. The ratio of protonated to deprotonated molecules is 1:1000 (1 protonated, 1000 deprotonated)
Thank you!!
Q1.
Apply henderson hasselbach equations
a)
pOH = pKb + log(BH+ / B)
since no pKb data is given, then assume pKb as a value
so...
half molecules protonated, means 1:1 ratio so 1/1 = 1
then
pOH = pKb + log(BH+ / B)
pOH = pKb + log(1)
pOH = pKb
pOH = 14-pH so:
14 - pH = pKb
pH = 14-pKb
b)
for 100:1 ratio then:
pOH = pKb + log(BH+ / B)
pOH = pKb + log(100/1)
pOH = pKb + 2
pOH = 14-pH
14- pH = pKb + 2
pH = 12-pKB
c)
similarly:
for 1:1000 ratio then:
pOH = pKb + log(BH+ / B)
pOH = pKb + log(1/1000)
pOH = 14-pH so:
14-pH = pKb + log(1/1000)
pH = 17 -pKb
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