Which one of the following statements is correct (assuming fGa-Si = fS-Br)?¨
The absorption band due to a Ga-Si bond occurs at a larger wavenumber than the absorption band due to a S-Br bond¨
The absorption band due to a Ga-Si bond occurs at a smaller wavenumber than the absorption band due to a S-Br bond
¨ None of the above
Solution :-
Ga-Si bond is weaker than S-Br bond because of the electronegativity differnces between the atoms.
Therefore the bond energy of the S-Br bond higher than Ga-Si bond
When the bond energy ishigher that means it need more eneregy for the absorption.
energy and wavelength are inversnaly proportional.
Therefore the
The absorption band due to a Ga-Si bond occurs at a larger wavenumber than the absorption band due to a S-Br bond
This is the correct statement.
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