Volume of air = volume of experiment chamber
Tempearture of air = temperature of boiling water
a)
for tempearture, we may assume so, since there is no longer heat transfer between each other... that is due to the gradient/change in temperature, if the temperature are equal, no more heat is required
so we ensure T1 = T2
b)
for the volume
we can assume so sinc the volume is fixed and therefore, the volume of water must be alwayus the same as the volume of the reservoir
this way we ansure that any material will occupy the same space/volume
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