13. Propane burns in air according to the following equation:
C3H8 (g) + 5 O2 (g) → 3 CO2 (g) + 4 H2O (g) ∆H = -2043 kJ
If 5.00 g of propane are reacted at a constant pressure of 1.15 atm leading to a change in volume of +8.6 L, calculate ∆E and the work done (in kJ). (MM C3H8 = 44.09 g/mol).
Using the information given (∆Hrxn = -2043 kJ) and any needed values from you text, calculate the ∆H o f for propane (C3H8).
Ans:
C3H8 (g) + 5 O2 (g) → 3 CO2 (g) + 4 H2O ∆H = -2043 kJ
P = 1.15 atm, w = 5 gm, ∆V = 8.6 L, MW of C3H8 = 44.06 g/mol
1) As system is doing work on the surroundings,
W = - P∆V = - 1.15 atm X 8.6 L = - 9.89 X 0.101325 KJ
Therefore, W = - 1.0021 KJ.
2) ΔHreaction = qat constant pressure = qreaction
Hence, q = - 2043 KJ
∆E = q + W = -2043 + (-1.0021)
= - 2.044 X 103 KJ.
3) ∆Ho = 5 X 10-3 kg X 1000 g/1 kg X 1 mol/44.09 g X – 2043 KJ/1 mol
= - 2.316 X 102 KJ.
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