Sucrose (C12H22O11, table sugar) is oxidized in the body by O2 via a complex set of reactions that ultimately produces CO2(g) and H2O(l) and releases 5.16 × 103 kJ of heat per mole of sucrose.
(a) Write a balanced thermochemical equation for this reaction. Include the physical state of each reactant and product.
Enter your answer for ΔHrxn in scientific notation.
(b) Calculate the energy change per gram of sucrose for this combustion reaction.
kJ/g
(a). Balanced thermochemical equation for this reaction is :
C12H22O11(s) + 12 O2(g) --------------> 12 CO2(g) + 11 H2O (l) , ΔHrxn = - 5.16 × 103 kJ
(b).
For the combustion of 1 mole of C12H22O11 , heat released = 5.16 x 103 KJ
Now, Mass of 1 mole of C12H22O11 = Number of moles x Gram molar mass = 1 mol x 342.3 g/mol = 342.3 g
Now, for the combustion of 342.3 g i.e. 1 mole of C12H22O11 ,heat released = 5.16 x 103 KJ
and
For the combustion of 1g of C12H22O11 , heat released = 5.16 x 103 KJ x 1g / 342.3 g = 15.07 KJ
Hence, Energy change per gram of sucrose for this combustion reaction = -15.07 KJ/g
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