Which type of distillation should be used to distill a mixture of 2-butanone and t-butyl alcohol, and why?
Which type of distillation should be used to distill diethylene glycol, and why?
Which type of distillation should be used to distill a mixture
of diethyl ether and chlorobenzene, and why?
1) Azeotropic Distillation
Boiling point of tertiary butyl alcohol is 82.2 0C
Boiling point of 2-butanone is 79.64 0C
The Azeotropic Distillation is used when the Boiling points of two components are near to equal.
The third component is used to lower the B.P. of one of the components.
2) Vacuum Distlillation
The B.P of Diethylene Glycol is 245 0C
This is antifreeze component. For removing water we required Vacuum Distlillation.
3) Extractive Distillation
Boiling point of diethyl ether is 34.6 0C
Boiling point of chlorobenzene is 131 0C
Extractive Distillation is used when the components have High B.P. and relatively Non-volatile component.
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