when in the bomb calorimeter experiment, we ignore any heat
transfer between the styrofoam cup and the hot water
so, in reality, some heat is lost to the styrofoam cup of the bomb
calorimeter
due to this the final equilibirum temperature is lower than what is
expected theoretically ( as some energy is lost from the
equation)
hence due to ignoring of this heat transfer, the equilibrium
temperature that is calculated theoretically is greater than the
practically measured equilibirum temeprature
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