Why silicon is hard and brittle while silicone is very soft?
Compared with pure metals and ionic salts, covalent solids such as silicon are hard and brittle because dislocations do not move in them except at high temperatures..silicon is bonded in a giant covalent lattice and has a tetrahedral structure, and is very hard to break apart.
silicones consist of an inorganic silicon-oxygen backbone chain (?-Si-O-Si-O-Si-O-?) with organic side groups attached to the silicon atoms. These silicon atoms are tetravalent. So, silicones are polymers constructed from inorganic-organic monomers.
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