Question

A 3 0.0 gram mixture containing 88.0% (by weight) of A and 12.0 % of B...

A 3 0.0 gram mixture containing 88.0% (by weight) of A and 12.0 % of B is recrystallized in water. The solubility of A and B in 100 mL of water is as follows:

   20 ̊ C       100 ̊C

A    1.5 g        6.0 g

B    0.75 g     4.0 g

a. Assuming that A and B do not affect each other’s solubility, c alculate the amount of water (in mL) that would be needed to obtain pure A . Show all work. Explain answers.

b. How much of pure A will be recovered? Show all work. Explain answers.

Homework Answers

Answer #1

As mentioned in question

a). Assuming that A and B do not affect each other’s solubility, c alculate the amount of water (in mL) that would be needed to obtain pure A . Show all work. Explain answers.

answer

A 3 0.0 gram mixture containing 88.0% (by weight) of A ,

so it 30 g * 88

A =26.4 g

12.0 % of B , So 30*12

B = 3.6 g

The solubility of A and B in 100 mL of water is as follows:

   20 ̊ C       100 ̊C

A    1.5 g        6.0 g

B    0.75 g     4.0 g

Recrystalisation means it sholud be complete soluble at hot condition, agin reform solids at cooling temperature.

so hot condition solubility for A is 6 g in 100 ml

we have to purify 26.4 g (as abovecalculated 88% in 30 g) of A, water required?

for 6 g required 100 ml water

26.4 g required water ?

=26.4 *100/6

=440 ml

so 440 ml required for A purification.

b).  How much of pure A will be recovered? Show all work. Explain answers.

Answer:

same above mentioed solubility

The solubility of A and B in 100 mL of water is as follows:

   20 ̊ C       100 ̊C

A    1.5 g        6.0 g

in recrystalization we have to cool the reaction mass, so at cooling 1.5 g in 100 ml.

but total we have 26.4 g and using 440 ml of water (above a answer),

so in 440 ml loss

=440*1.5/100

= 6.6 g would be loss due to its solubility (it present in filter mls water).

so the amount of pure compound will get after recrystalization

= 26.4 g -6.6 g

=19.8 g.

pure compound of A will recover 19.8 g

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
1. What is the purpose of crystallization in an organic chemistry procedure? 2. Using the solubility...
1. What is the purpose of crystallization in an organic chemistry procedure? 2. Using the solubility data you found for benzoic acid, calculate the volume of water required to dissolve 1.0 g of benzoic acid at room temperature. Calculate the volume of boiling water needed to dissolve 1.0 g of benzoic acid. 3. Explain why a Büchner or Hirsh funnel is used to isolate the final crystallized product instead of stem funnel. 4. Explain when a mixture of solvents would...
“Salt” (NaCl) is known to be readily soluble in water, however there is a limit to...
“Salt” (NaCl) is known to be readily soluble in water, however there is a limit to its solubility. The solubility of salt in water at 25° C is 35.9 g/100 mL. (3 x 5 points) a. Explain what the value 35.9 g/100 mL means. b. Write this value as two conversion factors. c. What minimum volume of water would be necessary to dissolve 2.2 kg of salt? (Show work)
A student reacted 100.0 mL of 0.9800 M HCl with 100.0 mL of 0.9900 M NH3....
A student reacted 100.0 mL of 0.9800 M HCl with 100.0 mL of 0.9900 M NH3. The density of                           the reaction mixture was 1.02 g/mL and the heat capacity was 4.016 J/g K.                           Calculate the enthalpy of neutralization by plotting and using the data shown below. Time(min) Temp(oC) 0.0 23.25 0.5 23.27 1.0 23.28 1.5 23.30 2.0 23.30 3.0 23.35 4.0 23.44 4.5 23.47 mix --------- 5.5 28.75...
B. Solubility Equilibrium: Finding a Value for Ksp 1. Volume 0.30 M Pb(NO3)2 = 5.0 mL.  ...
B. Solubility Equilibrium: Finding a Value for Ksp 1. Volume 0.30 M Pb(NO3)2 = 5.0 mL.   Number of moles Pb2+ = [M x V(stock sln)] = 0.0015 moles 2. a. Volume 0.30 M HCl used: 5.0 mL b. Number of moles Cl- added: 0.0015 moles 3. Observations: a. in hot water: the solid settled on the bottom then completely dissolved b. in cold water: No change, it stayed dissolved 4. Volume H2O added to dissolve PbCl2: 4.0 mL a. Total...
Imagine that you have two cups, one containing 1540 g of water and the other one...
Imagine that you have two cups, one containing 1540 g of water and the other one containing some amount of an unknown liquid. The specific heat of water is 4.19 J/g·°C, and the specific heat of the unknown liquid is 7.03 J/g·°C. You use two identical immersion heaters to heat the water and the unknown liquid simultaneously. Assume that all the heat from the heater is used to heat the content of the cups. (a) You started heating the water...
Inorganic questions--please show work and only answer if you truly understand it: Please show all work...
Inorganic questions--please show work and only answer if you truly understand it: Please show all work and answers on this page if at all possible. 5. Arrange the following solutions in order of decreasing freezing point, and explain your reasoning: 0.50 m HCl, 0.50 m glucose, 0.50 m acetic acid. 6. The alcohol content of hard liquor is normally given in terms of the “proof”, which is defined as twice the percentage by volume of ethanol (C2H­5OH) present. Calculate the...
3- CN$(aq) + NH4+(aq)↔ HCN(aq)+ NH3(aq) A solution is prepared with all reactants at 0.45 M...
3- CN$(aq) + NH4+(aq)↔ HCN(aq)+ NH3(aq) A solution is prepared with all reactants at 0.45 M and all products at 0.25 M. a) Calculate ΔG° and K (at 298K). b) Calculate Q and ΔG and indicate in what direction the reaction will proceed. c) Determine the concentrations once equilibrium is reached. d) What would be the effect of heating the solution at equilibrium? EXPLAIN your reasoning. -----------------------------------Give detail Show ALL WORK, UNITS and use ICE/reaction table and ML (no millimoles)....
Please answer only if you 100% know and it has to be all of them! Please...
Please answer only if you 100% know and it has to be all of them! Please show work neatly!!! :)Thanks! 1. Calculate the molarity, molality and mass % of NH3 in a solution in which 60.0g of NH3 are dissolved in 140.0g of water. The Density of this solution is 0.982g/mL 2. A solution is prepared by dissolving 38.0g of non-volatile molecular solute in 125 grams of benzene. The boiling point of this solution is 84.5C (Celsius) and the boiling...
a)How is it possible to determine if CaCO3 is Cl- free after synthesis? b)How can the...
a)How is it possible to determine if CaCO3 is Cl- free after synthesis? b)How can the Cl- ions be remove from CaCO3 after synthesis? I should answer the questions from the following experiment but if you know the answer and you are sure, yo do not need to read experiment. Please answer correctly because i hav no chance to make wrong :(((( Physical and Chemical Properties of Pure Substances Objective The aim of today’s experiment is to learn handling chemicals...
CHE 151-3rd Write your answers in the Blue Book provided. Start each new question at the...
CHE 151-3rd Write your answers in the Blue Book provided. Start each new question at the top of a new page. To receive full credit for problems, you must show the correct setup with units and give your answer with the correct number of significant figures. 1.a) A barometer reads 1.43 atm. Calculate the pressure in mm Hg, and torr. b) If 4.50 L of oxygen is cooled at constant pressure from 200 oC to 25 oC, what is the...