A 3 0.0 gram mixture containing 88.0% (by weight) of A and 12.0 % of B is recrystallized in water. The solubility of A and B in 100 mL of water is as follows:
20 ̊ C 100 ̊C
A 1.5 g 6.0 g
B 0.75 g 4.0 g
a. Assuming that A and B do not affect each other’s solubility, c alculate the amount of water (in mL) that would be needed to obtain pure A . Show all work. Explain answers.
b. How much of pure A will be recovered? Show all work. Explain answers.
As mentioned in question
a). Assuming that A and B do not affect each other’s solubility, c alculate the amount of water (in mL) that would be needed to obtain pure A . Show all work. Explain answers.
answer
A 3 0.0 gram mixture containing 88.0% (by weight) of A ,
so it 30 g * 88
A =26.4 g
12.0 % of B , So 30*12
B = 3.6 g
The solubility of A and B in 100 mL of water is as follows:
20 ̊ C 100 ̊C
A 1.5 g 6.0 g
B 0.75 g 4.0 g
Recrystalisation means it sholud be complete soluble at hot condition, agin reform solids at cooling temperature.
so hot condition solubility for A is 6 g in 100 ml
we have to purify 26.4 g (as abovecalculated 88% in 30 g) of A, water required?
for 6 g required 100 ml water
26.4 g required water ?
=26.4 *100/6
=440 ml
so 440 ml required for A purification.
b). How much of pure A will be recovered? Show all work. Explain answers.
Answer:
same above mentioed solubility
The solubility of A and B in 100 mL of water is as follows:
20 ̊ C 100 ̊C
A 1.5 g 6.0 g
in recrystalization we have to cool the reaction mass, so at cooling 1.5 g in 100 ml.
but total we have 26.4 g and using 440 ml of water (above a answer),
so in 440 ml loss
=440*1.5/100
= 6.6 g would be loss due to its solubility (it present in filter mls water).
so the amount of pure compound will get after recrystalization
= 26.4 g -6.6 g
=19.8 g.
pure compound of A will recover 19.8 g
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