Question

What problem would be encountered if you tried to dissolve Ag2O with HCl solution?

What problem would be encountered if you tried to dissolve Ag2O with HCl solution?

Homework Answers

Answer #1

Precipitate silver chloride from nitric or sulphuric acids we used to pour a solution of table salt in water into the acid until the cloudiness ceased to be produced. At this point, the precipitate was silver chloride.

1)So, I believe that adding the HCl will cause your silver to precipitate as chloride.
2)Since the AgNO3 -> Ag & NO3 ions in solution,
by adding Cl ions, you form the insoluble AgCl, hence precipitation
3)Don't know how you'd go recycling the nitric, as liquid HCl is ~66% water, your solution will get weaker and weaker every precipitation. If you compensate with strong nitric at the start and your nitric concentration is too high you can oxidise the silver -> silver oxide .

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