Question

Show using chemical equations how successive deprotonation of (Cu(OH2)2(NH3)2)2+ produces an oxoacid

Show using chemical equations how successive deprotonation of (Cu(OH2)2(NH3)2)2+ produces an oxoacid

Homework Answers

Answer #1

First I think the complex has to be an octahedral one so no of NH3 ligands has to be 4 not 2.(Cu(OH2)2(NH3)4)2+

According to the question given,deprotonation occurs as follows.

Deprotonation is caused by the high charge density on the central action which weakens the O-H bonds in water (H2O) ligands and enables the H+ to leave.

According to that,the complex is dark blue in colour

(Cu(OH2)2(NH3)2)2+ + OH- (Cu(OH2)(OH)(NH3)2)+ +H2O

Further deprotonation gives,

(Cu(OH2)(NH3)2) + 2H2O

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
The logarithmic stepwise formation constants for the substitution of [Cu(OH2)6]2+ with ethylenediamine (en) to form the...
The logarithmic stepwise formation constants for the substitution of [Cu(OH2)6]2+ with ethylenediamine (en) to form the ions [Cu(en)(OH2)4]2+, [Cu(en)2(OH2)2]2+, [Cu(en)3]2+ are 10.5, .0, and -1.0 respectively. a. Account for this drastic increase in successive formation using your knowledge of coordination complexes and their electronic structures. (Hint: draw a crystal field splitting diagram to justify your answer).
what are the concentrations of Cu2+, NH3, and Cu(NH3)4^2+ at equilibrium when 18.8g of cu(NO3)2 iS...
what are the concentrations of Cu2+, NH3, and Cu(NH3)4^2+ at equilibrium when 18.8g of cu(NO3)2 iS added to 1.0L of a .800M solution of aqueous ammonia? Assume that the reaction goes to completion and forms Cu(NH3)4^2+ Kf=2.0e12
(A) Using the Ksp for Cu(OH)2 (1.6 x 10^-19) and the overall formation constant for Cu(NH3)4...
(A) Using the Ksp for Cu(OH)2 (1.6 x 10^-19) and the overall formation constant for Cu(NH3)4 (1.0 x 10^13), calculate a value for the equilibrium constant for the reaction: Cu(OH)2(s) + 4NH3(aq) <===> Cu(NH3)4(aq) + 2OH-(aq) (B) Use the value of the equilibrium constant you calculated in Part A to calculate the (approximate) solubility (in mols/liter, M) of Cu(OH)2 in 5.0 M NH3. In 5.0 M NH3 the concentration of OH- is 9.5 x 10^-3 M. (Although not strictly correct...
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.400...
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.400 M NH3. What are the concentrations of Cu2 , NH3, and Cu(NH3)42 at equilibrium? The formation constant*, Kf, of Cu(NH3)42 is 1.70 × 1013. Can someone explain all of the steps to me including the steps right after the ICE table please i dont get how to solve for x.
The complex ion Cu(NH3)42 is formed in a solution made of 0.0400 M Cu(NO3)2 and 0.500...
The complex ion Cu(NH3)42 is formed in a solution made of 0.0400 M Cu(NO3)2 and 0.500 M NH3. What are the concentrations of Cu2 , NH3, and Cu(NH3)42 at equilibrium? The formation constant*, Kf, of Cu(NH3)42 is 1.70 × 1013.
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.500...
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.500 M NH3. What are the concentrations of Cu2 , NH3, and Cu(NH3)42 at equilibrium? The formation constant*, Kf, of Cu(NH3)42 is 1.70 × 1013.
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.400...
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.400 M NH3. What are the concentrations of Cu2 , NH3, and Cu(NH3)42 at equilibrium? The formation constant*, Kf, of Cu(NH3)42 is 1.70 × 1013.
Copper(I) ions in aqueous solution react with NH3(aq) according to Cu+(aq) + 2NH3 (aq) --> Cu(NH3)2...
Copper(I) ions in aqueous solution react with NH3(aq) according to Cu+(aq) + 2NH3 (aq) --> Cu(NH3)2 Kf = 6.3*10^10 Calculate the solubility (in g
Write the equations that correspond to the chemical changes that occured on treating each of the...
Write the equations that correspond to the chemical changes that occured on treating each of the carbonate/hydroxide precipitates [1) Fe (III), [2) Cu(II), [3) Zn(II), and 4) Ag (I] with A) 6M NH3 (if no reaction occurs, write NR) B) 6M NaOH (If no reaction occurs, write NR)
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.400...
The complex ion Cu(NH3)42 is formed in a solution made of 0.0300 M Cu(NO3)2 and 0.400 M NH3. What are the concentrations of Cu2 , NH3, and Cu(NH3)42 at equilibrium? The formation constant*, Kf, of Cu(NH3)42 is 1.70 × 1013. This is what the hint gave me, Since the formation constant, Kf, is very large, it can be assumed that the reaction goes nearly to completion to form Cu(NH3)42 . Cu2 is the limiting reagent and will be used up...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT