Before the first endpoint only K3PO4 is reacting.
PO43–(aq) + H3O+(aq) -----> HPO42–(aq) + H2O (l)
If at the first equivalence point 14.91 ml of 0.1206 M HCl is consumed, how many mmol of K3PO4 were present in the sample? Round your answer to 3 decimal places.
mmol of K3PO4 present = 1.798 mmol
Explanation
At first equivalence point, the reaction between HCl and K3PO4 is given as
HCl (aq) + K3PO4 (aq) K2HPO4 (aq) + KCl (aq)
Given : molarity of HCl = 0.1206 M
volume of HCl = 14.91 mL
mmoles of HCl = (molarity of HCl) * (volume of HCl (mL))
mmoles of HCl = (0.1206 M) * (14.91 mL)
mmoles of HCl = 1.798 mmol
From the reaction equation, mmol of K3PO4 present = mmol of HCl consumed
or mmol of K3PO4 present = 1.798 mmol
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