a.) Phosphoric acid is a triprotic acid: H3PO4(aq) +H2O(l) ↔ H3O+(aq) + H2PO4-(aq) Ka1 = 7.5 x 10-3 H2PO4-(aq) +H2O(l) ↔ H3O+(aq) + HPO42-(aq) Ka2 = 6.2 x 10-8 HPO42-(aq) +H2O(l) ↔ H3O+(aq) + PO43-(aq) Ka3 = 4.8 x 10-13 Determine whether sodium monohydrogen phosphate (Na2HPO4) is neutral, basic, or acidic. First, what is its Ka when it acts as an acid?
b.) Second, what is its Kb when it acts as a base?
c.) Finally, indicate whether the HPO42- ion is neutral, basic, or acidic in solution.
a)For the the ion that dissociates is the one to analizes
HPO42- has a Ka of 6.2x10-8, its pKa=-logKa=7.20
That pKa indicates that the ion is a neutral ion (from the pH scale near 7 is neutral),when it act as an acid its Ka is the one indicated
b) when it act as a base
c) has a more basic behavior because it pKa=-log(4.8x10-3)=12.32, it is in the basic range in the pH scale
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