Question

A classic experiment in equilibrium studies dating from 1862 involved the reaction in aqueous solution of...

A classic experiment in equilibrium studies dating from 1862 involved the reaction in aqueous solution of ethanol and acetic acid to produce ehty1 acetate and water

C2H5OH(aq)+CH3COOH(aq)<=>CH3COOC2H5(aq)+H2O(l)

The reaction can be followed by analtzing the equilibrium mixture for its acetic acid content using a titration with Ba(OH)2 as shown below:

2CH3COOH(aq)+Ba(OH)2(aq)<=>Ba(CH3COO)2(aq)+2H2O

In one experiment, a mixture of 1 moles acetic acid and 0.5 moles ethanol is brought to equilibrium in a 1 L flask. A 20 mL sample of the equilibrium mixture requires 56.74 mL of 0.1 M Ba(OH)2 for its titration.

What is the mass action expressin for the reaction of ethanol and acetic acid?

what is the value of the equilibrium constant for the reaction of ethanol and acetic acid?

Homework Answers

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
A classic experiment in equilibrium studies dating from 1862 involved the reaction in aqueous solution of...
A classic experiment in equilibrium studies dating from 1862 involved the reaction in aqueous solution of ethanol and acetic acid to produce ethyl acetate and water. C2H5OH(aq) + CH3COOH(aq) <=> CH3COOC2H5(aq) + H2O(l) The reaction can be followed by analyzing the equilibrium mixture for its acetic acid content using a titration with Ba(OH)2 as shown below: 2CH3COOH(aq) + Ba(OH)2(aq) -> Ba(CH3COO)2(aq) + 2H2O(l) In one experiment, a mixture of 1.000moles acetic acid and 0.5000 moles ethanol is brought to equilibrium...
The equilibrium constant for the esterification of ethanol and aceticacid in an aqueous solution CH3COOH(aq) +...
The equilibrium constant for the esterification of ethanol and aceticacid in an aqueous solution CH3COOH(aq) + C2H5OH(aq) -----> CH3COOC2H5(aq) + H2O(l) amounts to 0.566 at 298 K. The reaction mixture initially contains 0.040 mol dm^−3 of acetic acid and 0.025 mol dm^−3 of ethanol. Find themolar concentration of ethyl acetate at the equilibrium. Assume that the pH is low enough that CH3COOH is not dissociated at all and thatthe activity of water equals 1 just like for pure liquid water...
Will rate for sure In Experiment 4, you will investigate the following reaction: CH3COOH (aq) +...
Will rate for sure In Experiment 4, you will investigate the following reaction: CH3COOH (aq) + NaOH (aq) → CH3COONa (aq) + H2O (l) You will add controlled amounts of sodium hydroxide to an acetic acid solution. Throughout the course of the reaction, the chemical species present in the reaction mixture will change, along with their concentration. To understand a titration experiment, it is important to know what species are present in the reaction mixture at a given time, as...
For all of the following questions 10.00mL of 0.187 M acetic acid (CH3COOH) is titrated with...
For all of the following questions 10.00mL of 0.187 M acetic acid (CH3COOH) is titrated with 0.100M KOH (The Ka of acetic acid is 1.80 x 10-5) Region 1: Initial pH Before any titrant is added to the starting material Tabulate the concentration of the species involved in the equilibrium reaction, letting x = [H+] at equilibrium (Do not calculate “x” yet) CH3COOH ⇌ H+(aq) CH3COO-(aq) Initial concentration (M) Change in concentration (M) -x +x +x Equilibrium concentration (M) Use...
1. A solution of nitrous acid, HNO2, was prepared by dissolving 1.93 g of HNO2 in...
1. A solution of nitrous acid, HNO2, was prepared by dissolving 1.93 g of HNO2 in 500.0 mL of solution. If the equilibrium concentration of H+ in this solution is 7.85 x 10-3 M, what is the equilibrium constant for the dissociation reaction: HNO2 ⇌ H+ + NO2- 2. For the following dissociation of acetic acid, K = 1.76 x 10-5: CH3COOH ⇌ CH3COO- + H+ Sodium acetate completely dissociates in solution according to the following reaction:NaCH3COO → Na+ +...
6. Consider the following balanced acid/base reaction: 2 CH3COOH +   Ba(OH)2 -> (CH3COO)2Ba   + 2 H2O...
6. Consider the following balanced acid/base reaction: 2 CH3COOH +   Ba(OH)2 -> (CH3COO)2Ba   + 2 H2O A student pipetted 5.00 mL of a 0.224M solution of CH3COOH into an Erlenmeyer flask. The student calculated that 36.44 mL Ba(OH)2 was needed to neutralize the acid. Calculate the molarity of Ba(OH)2 in the unknown solution.               7. In an aqueous solution the [H3O+] is 2.77x 10-9.M.            a. Is this solution acidic, basic or neutral?         b. What is the...
Chemical reactions: Mol/Gram conversions: a.) According to the following reaction, how many grams of hydrogen gas...
Chemical reactions: Mol/Gram conversions: a.) According to the following reaction, how many grams of hydrogen gas are necessary to form 0.695 moles ammonia? N2 (g) + 3H2(g) 2NH3 (g). __________grams hydrogen gas b.) According to the following reaction, how many moles of calcium chloride will be formed upon the complete reaction of 25.6 grams of calcium hydroxide with excess hydrochloric acid? Ca(OH)2(aq) + HCl (aq) CaCl2 (aq) + 2H2O (l) __________moles calcium chloride c.) According to the following reaction, how...
Watch the animation in the first hint. Then answer the following questions about the below reaction:...
Watch the animation in the first hint. Then answer the following questions about the below reaction: Ca(OH)2​(aq)+2HCl(aq)--> CaCl2​(aq)+H2​O(l) An aqueous solution of Ca(OH)2with a concentration of 0.167 M was used to titrate 25.00 mL of aqueous HCl. 11.43 mL of the Ca(OH)2was required to reach the endpoint of the titration. How many moles of base were required to react completely with the acid in this reaction? ____mol Ca(OH)2 How many moles of HCl were present in the original 25.00 mL...
Acetate buffer is often used as a buffer solution for protein studies at acidic pH (from...
Acetate buffer is often used as a buffer solution for protein studies at acidic pH (from 3.6 to 5.6). The dissociation reaction is: CH3COOH <---> CH3COO- + H+ Here CH3COOH (abbreviated as HOAc) and the acetate anion CH3COO- (abbreviated as OAc-) are the conjugate acid-base pair. a.) Suppose you prepared an acetate buffer containing 0.1M of HOAc and 0.1M of OAc-. What are the [H+] and pH of this solution? b.) Now you add 0.01M HCl to your acetate buffer....
In an experiment, 400 mL of each solution is taken, and 0.00900 mol of HCℓ is...
In an experiment, 400 mL of each solution is taken, and 0.00900 mol of HCℓ is added to each. Match the descriptions below with the correct values that apply after the addition of HCℓ to these two buffer samples. Buffer 1 Buffer 2 CH3COOH present 0.450 mol 0.00450 mol CH3COO- present 0.450 mol 0.00450 mol pH 4.74 4.74 Is Buffer 1 still a functional buffer after addition of HCl? Yes or no? mol of acetate remaining in Buffer 2 after...