Question

Please show work. I am confused about how to get there. When ignited, solid ammonium dichromate...

Please show work. I am confused about how to get there.

When ignited, solid ammonium dichromate decomposes in a fiery display. This is the reaction for a "volcano" demonstration. The decomposition produces nitrogen gas, water vapor, and chromium(III) oxide. The temperature is constant at 25°C.

Substance

ΔHf° (kJ/mol)

S° (kJ/mol K)

Cr2O3(g)

–1147

0.08120

H2O(l)

–242

0.1187

N2(g)

0

0.1915

(NH4)2Cr2O7(s)

–22.5

0.1137

Determine Δ S univ° (in kJ/mol K).

a.

84.3

b.

6.03

c.

5.22

d.

7.66

e.

6.39

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