KNO3(s)= K+(aq) +NO3-(aq)
Ksp=[K+(aq)][NO3-(aq)]
Equation of line= -0.0003x+0.0039
Volume total(L) | T (°C) | [KNO3] (M) | Ksp | ln Ksp | 1/T (1/K) |
0.0250 | 67.20 | 6.57 | 43.138624 | 3.764419 | 0.002938 |
0.0292 | 56.00 | 5.62 | 31.621364 | 3.453833 | 0.003038 |
0.0334 | 46.70 | 4.92 | 24.168705 | 3.185059 | 0.003126 |
0.0376 | 39.90 | 4.37 | 19.070875 | 2.948162 | 0.003194 |
0.0418 | 36.80 | 3.93 | 15.430988 | 2.736378 | 0.003226 |
0.0461 | 33.30 | 3.56 | 12.686577 | 2.540544 | 0.003263 |
0.0510 | 29.80 | 3.22 | 10.365875 | 2.338519 | 0.003301 |
a. The equation can be represented in the following form: ln Ksp = -deltaH/R ( 1/T ) + deltaS/R . Based on your equation, calculate values of Delta H and Delta S and include units. Provide a molecular level explanation to account for the signs of DH and DS.
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