Question

KNO3(s)= K+(aq) +NO3-(aq) Ksp=[K+(aq)][NO3-(aq)] Equation of line= -0.0003x+0.0039 Volume total(L) T (°C) [KNO3] (M) Ksp ln...

KNO3(s)= K+(aq) +NO3-(aq)

Ksp=[K+(aq)][NO3-(aq)]

Equation of line= -0.0003x+0.0039

Volume total(L) T (°C) [KNO3] (M) Ksp ln Ksp 1/T (1/K)
0.0250 67.20 6.57 43.138624 3.764419 0.002938
0.0292 56.00 5.62 31.621364 3.453833 0.003038
0.0334 46.70 4.92 24.168705 3.185059 0.003126
0.0376 39.90 4.37 19.070875 2.948162 0.003194
0.0418 36.80 3.93 15.430988 2.736378 0.003226
0.0461 33.30 3.56 12.686577 2.540544 0.003263
0.0510 29.80 3.22 10.365875 2.338519 0.003301

a. The equation can be represented in the following form: ln Ksp = -deltaH/R ( 1/T ) + deltaS/R . Based on your equation, calculate values of Delta H and Delta S and include units. Provide a molecular level explanation to account for the signs of DH and DS.

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