The best time is now as you will have many experts online. But it depends on your question, that you will get the answer within an hour or not. If it has all the relevant informations and is comparatively less difficult to do, then chances are high that you will get solution pretty quick. An upper bound to the time of getting solution is difficult to formulate. But stick to the rules mentioned. Ask straight forward questions and avoid research based queries to get quick responses.
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