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In transitions between vibrational energy levels of the diatomic molecule HBr (hydrogen bromide), photons are emitted...

In transitions between vibrational energy levels of the diatomic molecule HBr (hydrogen bromide), photons are emitted with energy 5.1×10^−21J, twice this energy, three times this energy, etc. Because the mass of the bromine nucleus is much larger than that of the hydrogen nucleus, it is a good approximation to consider the bromine nucleus to be always at rest; you can think of the H atom as being attached by a “spring” to a wall. What is the effective spring stiffness of the HBr bond?

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