You should know that electric field inside the medium is always zero and charge is always reside on its surface i.e. there is no charge inside it. But there constant potential V =Va -Vb. We have to find E but for that we have to know the charge Q on the inner shell that's why in the calculation Q has founded in the form of V .But Q-enc in the calculation doesn't mean charge enclosed in the conductive medium it's the charge on the inner shell .Since we have calculated for the charge on the inner shell we don't require permittivity of the conductive medium.
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