due to transistion of electrons from one energy level to another level visible radiation is produced.
when ever there is a absorption of photon in the range of 0.001ev then it is in the range of micro waves so when ever the photon of micro wave range is absoption then there is a change in the molecule which leads to the rotation of molecule.
This energy of photon is sufficient for the rotation of molecule.
so the energy levels involved in this case are rotational energy levels.
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