Question

Recall the number of particles in the ground state E0 = 0 given by N0 =...

Recall the number of particles in the ground state E0 = 0 given by

N0 = (g0)/(eαeE0/kT − 1) = (1)/(eα − 1)

Show that N0 ≈ 1/α for small values of α.

Homework Answers

Answer #1

☞Since   , in the question.

→Expanding the exponential term , we get

Because,

Now, for small values of , the terms , ... and all higher orders are very very small and are neglected.( for small value of )

So we are left with only

or

Hence proved.

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Use the Boltzmann equation to calculate the excited state to ground state population ratio (to 1...
Use the Boltzmann equation to calculate the excited state to ground state population ratio (to 1 significant figure) for Cl2: N(ν=1)/N(ν=0) at room temperature (25°C). The wavenumber for the fundamental vibrational frequency of Cl2 is 550 cm-1. Assume that g1 ≈ g0
The ground state of a particle is given by the time‐dependent wave function Ψ0(x, t) =...
The ground state of a particle is given by the time‐dependent wave function Ψ0(x, t) = Aeαx^2+iβt​​​​​​ with an energy eigenvalue of E0 = ħ2α/m a. Determine the potential in which this particle exists. Does this potential resemble any that you have seen before? b. Determine the normalization constant A for this wave function. c. Determine the expectation values of x, x2, p, and p2. d. Check the uncertainty principle Δx and Δp. Is their product consistent with the uncertainty...
Consider a system of distinguishable particles with five states with energies 0, ε, ε, ε, and...
Consider a system of distinguishable particles with five states with energies 0, ε, ε, ε, and 2ε (degeneracy of the states has to be determined from the given energy levels). Consider ε = 1 eV (see table for personalized parameters) and particles are in equilibrium at temperature T such that kT =0.5 eV: (i) Find the degeneracy of the energy levels and partition function of the system. (iii) What is the energy (in eV) of N = 100 (see table)...
Given the folloiwng two half-reactions: Fe3+ (aq) + 3 e− --> Fe (s)             E0 =...
Given the folloiwng two half-reactions: Fe3+ (aq) + 3 e− --> Fe (s)             E0 = −0.036 V Mg2+(aq) + 2 e− --> Mg (s) E0 = −2.37 V Calculate cell potential (Ecell) for a voltaic cell when [Fe3+] = 1.0 *10-3 M, [Mg2+] = 2.50 M at 25 oC Hint: (1) Write the overall redox reaction and count the number of electrons transferred; (2) determine the cell potential for a voltaic cell; (3) Calculate Q; (4) Plug in the...
In the Zn2+ cation, in its ground state, how many electrons have ml = 0 and...
In the Zn2+ cation, in its ground state, how many electrons have ml = 0 and s = +1/2?
In the Zn2+ cation, in its ground state, how many electrons have ml = 0 and...
In the Zn2+ cation, in its ground state, how many electrons have ml = 0 and s = +1/2?
In the Sr2+ cation, in its ground state, how many electrons have both ml = 0...
In the Sr2+ cation, in its ground state, how many electrons have both ml = 0 and s = -1/2 ?
Recall that (by the Fundamental Theorem of Algebra) the only polynomial P(t) of degree n−1 that...
Recall that (by the Fundamental Theorem of Algebra) the only polynomial P(t) of degree n−1 that vanishes at n distinct points t1,...,tn ∈ R is P(t) ≡ 0. Using this, show that given any values b1,...,bn ∈ R, there is a polynomial Q(t) = ξ1 + ξ2t + ... + ξntn-1 such that Q(ti) = bi (and thus Q(t) takes precisely the given values at the given points). Hint: Show that the coefficient matrix of the corresponding system is nonsingular.
The state of a many body system is characterized by two quantum numbers, n and m....
The state of a many body system is characterized by two quantum numbers, n and m. The possible values of the quantum number n are 0, 1, 2, ∞, while the values of m are in the range 0,1,,n. The energy of the system in the state (n,m) is nω and the number of particles is m. Evaluate the grand partition function for this system.
(I) What is the full ground state electron configuration for a neutral atom with ? =...
(I) What is the full ground state electron configuration for a neutral atom with ? = 22 protons? (II) A hydrogen atom with a principal quantum number of ? = 4. a. write all the possible values for the other quantum numbers. b. calculate the total number of possible quantum states that can exist for this principal quantum state. (III) An excited hydrogen atom is in the 6?1 state. a. What is the principal quantum number of the electron? b....