Obtain an expression for the compressibility of (a) an ideal gas, (b) for a gas obeying the Van der Waals equation of state.
A)
B) Van der Waals equation of state is
Where and are constants which are different for different gases. Isothermal compressibility is defined as
Differentiating the Van der Waals equation wrt pressure we get
This implies
Coefficient of thermal expansion is given as
Differentiating the Van der Waals equation wrt temperature at constant pressure we get
Solving this we get
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