Under constant pressure, the temperature of 1.70 mol of an ideal monatomic gas is raised 15.5 K. (a) What is the work W done by the gas? J (b) What is the energy transferred as heat Q? J (c) What is the change ΔEint in the internal energy of the gas? J (d) What is the change ΔK in the average kinetic energy per atom? J
a)At constant pressure, work done by gas
W = nR ΔT
n is number of moles of gas, R (gas constant) = 8.3
so W = 1.7 x 8.3 x 15.5 = 218.7 J
b) At constant pressure Q = n Cp ΔT
Cp is molar specific heat at constant pressure and =
(f+2)R/f
f is degree of freedom. for monoatomic gas f = 3
So Q = 1.7 x 8.3 x (5/3) 15.5 = 364.5 J
c) Q = ΔE + W
hence ΔE = Q - W = 145.8 J
d) Kinetic energy per atom = f Kb T/2
Kb = R/Na , Na is avogadro number
( 6.2 x 1023 )
so change in KE per atom ΔK = f Kb ΔT /2
= 3 x 8.3 15.5 / 2 x 6.2 x
1023 = 3.1x10-22 J
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