Initially at a temperature of 90.0 ∘C, 0.220 m3 of air expands at a constant gauge pressure of 1.31×105 Pa to a volume of 1.50 m3 and then expands further adiabatically to a final volume of 2.35 m3 and a final gauge pressure of 2.23×104 Pa. Compute the total work done by the air. CV for air is 20.8 J/(mol⋅K) .
initial temperature=T1=273+90=
363 K
initial volume=V1=0.22 m^3
initial pressure P1=1.31*10^5+101325=232325 Pa
at the end of first process,
pressure=P2=P1=232325 Pa
volume=V2=1.5 m^2
then work done=P1*(V2-V1)=232325*(1.5-0.22)=297376 J
second process:
at the beginning of the second process which is adiabatic in nature,
initial volume=V2=1.5 m^3
initial pressure=P2=232325 Pa
final volume=V3=2.35 m^3
final pressure=P3=2.23*10^4+101325=123625 Pa
work done in adabatic process=(P3*V3-P2*V2)/(1-gamma)
where gamma=Cp/Cv
=(Cv+R)/Cv
=(20.8+8.314)/20.8=1.3997
hence work done=(123625*2.35-232325*1.5)/(1-1.3997)
=145030.648 J
hence total work done=297376 +145030.648=442406.6480 J
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