Question

Consider a system of N distinguishable atoms, each of which can be in only one of...

Consider a system of N distinguishable atoms, each of which can be in only one of two states: the lowest energy state with energy 0, and an excited state with energy ɛ > 0. When there are n atoms in the excited state (and N-1 atoms in the lowest state), the total energy is U = nɛ.

1. Calculate the entropy S/k = ln(Ω(n)) and find the value of n for which it is maximum.

2. Find an expression for temperature T as a function of n, N, and ɛ.

Homework Answers

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Consider a system of distinguishable particles with five states with energies 0, ε, ε, ε, and...
Consider a system of distinguishable particles with five states with energies 0, ε, ε, ε, and 2ε (degeneracy of the states has to be determined from the given energy levels). Consider ε = 1 eV (see table for personalized parameters) and particles are in equilibrium at temperature T such that kT =0.5 eV: (i) Find the degeneracy of the energy levels and partition function of the system. (iii) What is the energy (in eV) of N = 100 (see table)...
Consider a system composed of two distinguishable free particles, each of which can have energy E...
Consider a system composed of two distinguishable free particles, each of which can have energy E = nε, for n = 0, 1, 2, .... List the microstates with energy E = 3ε.
Consider a system composed of a very large number (N >>1) of indistinguishable atoms, each of...
Consider a system composed of a very large number (N >>1) of indistinguishable atoms, each of which has only two energy levels 0 and . In thermodynamic equilibrium, there are n particles each with energy  and the total energy of the system is E. (10 points) a) Write and equation for the number of microstates  in terms of N, E, and . b) Use the Stirling approximation to write an equation for the entropy S. E 1 and...
A molecule has three degenerate excited vibrational states, each with excitation energy ? above the ground...
A molecule has three degenerate excited vibrational states, each with excitation energy ? above the ground state. a) At temperature T, what is the ratio between the number of molecules in (all of) these vibrational states and the number in the ground state? b) At very high T, what is this ratio? c) Assume you have N distinguishable molecules of this type. Use the free energy to compute entropy S/k of the system at temperature T d) Compute the number...
A. Consider a hydrogen atom with one electron and quantized energy levels. The lowest energy level...
A. Consider a hydrogen atom with one electron and quantized energy levels. The lowest energy level (n = 1) is the ground state, with energy -13.6 eV. There are four states corresponding to the next lowest energy (n = 2), each with energy-3.4 eV. For the questions below, consider one of these four states, called one of the first excited states. 2. Assume that this hydrogen atom is present in a gas at room temperature (T ~ 300 K, kBT...
A system consists of N = 106 particles that can occupy two energy levels: a nondegenerate...
A system consists of N = 106 particles that can occupy two energy levels: a nondegenerate ground state and a three-fold degenerate excited state, which is at an energy of 0.25 eV above the ground state. At a temperature of 960 K, find the number of particles in the ground state and in the excited state.
Derive the Sacker-Tetrode Equation which is the entropy expression for N indistinguishable ideal gas atoms of...
Derive the Sacker-Tetrode Equation which is the entropy expression for N indistinguishable ideal gas atoms of total energy U in a container of volume V.
1. Consider a three level system in which the energies are equally spaced (by energy ε);...
1. Consider a three level system in which the energies are equally spaced (by energy ε); each of the levels has certain (nonzero) degeneracy g . A. Write down the general expression for the average energy and the partition function of the system. B. Compute the occupations for ε = kT, when (i) all the states are singly degenerate and (ii) when the degeneracies are g0 = 1, g1 = 1, g2 = 3. Here gj represents the degeneracy of...
Assume you have a system that can have one of six distinct energy states E1 E2...
Assume you have a system that can have one of six distinct energy states E1 E2 E3 E4 E5 E6 what is the entropy of an ensemble of five systems where one system is in energy state E2 three systems are in energy state E3 and one system is in energy state E6. Choose the correct answer S= Kb ln(120) S= Kb ln(24) S= Kb ln(20) S= Kb ln(5) S= Kb ln(2) S=0
Consider a molecule that can be in one of two different conformation states A or B....
Consider a molecule that can be in one of two different conformation states A or B. These states are two different arrangements of the atoms: e.g., in state B, one part of the molecule could be rotated about a bond with respect to the rest of the molecule. Assume the energies of states A and B are 4e-21 and 8e-21 J respectively. At room temperature, T = 298 K, what is the relative likelihood of the molecule being found in...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT