Problem: Mercury fills 90% of the volume of a sealed glass container at 20 ?C. What temperature does the glass/Mercury have to be heated so that the mercury completely fills the container? (?Hg = 6x10-5 ?C-1, and ?glass = 0.4x10-5C-1). Show all working.
We have Vm = 0.9Vg (Initial volumes)
We want to heat the mercury and glass till the mercury completely fills the glass container.
Which means V'm = V'g
which are the respective final volumes.
The initial temperature = Ti = 20 oC = 20 + 273 = 293 K.
Let us denote the final temperature as Tf
Now, the volume expansion equation is given as
For mercury
For glass
Equating V'm = V'g, we get
0.9(1 + 3 * 6x10-5(Tf - 293)) = 1 + 3*0.4x10-5(Tf - 293)
0.9 + 16.2x10-5(Tf - 293) = 1 + 1.2x10-5(Tf - 293)
15x10-5(Tf - 293) = 0.1
Tf - 293 = 666.67
Tf = 959.67 K
Ans. The glass/mercury needs to be heated upto 959.67 K or 686.67 oC.
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