--Given Values--
Atomic Radius (nm) = 0.116
FCC Metal = Gold
BCC Metal: = Sodium
Temperature ( C ) = 1017
Metal A = Tin
Equilibrium Number of Vacancies (m-3) = 6.02E+23
Temperature for Metal A = 369
Metal B = Gallium
1) If the atomic radius of a metal is the value shown above and it
has the face-centered cubic crystal structure, calculate the volume
of its unit cell in nm3? Write your answers in
Engineering Notation.
Your Answer =
2) What is the atomic packing factor for the BCC crystal
structure?
Your Answer =
3) Find the theoretical density for the FCC Element shown above in
g/cm3. Write your answer to the ten thousandths place
(0.0000):
Your Answer =
4) Calculate the atomic radius, in nm, of the BCC Metal above
utilizing the density and the atomic weight provided by examination
booklet - Write your answer with 4 significant
figures:
Your Answer =
5) Calculate the fraction of atom sites that are vacant for copper
(Cu) at the temperature provided above. Assume an energy for
vacancy formation of 0.90 eV/atom:
Your Answer =
6) Repeat the calculation in question 5 at room temperature (25
C):
Your Answer =
7) Calculate the energy (in eV/atom) for vacancy formation for the
Metal A and the equilibrium number of vacancies at the temperature
provided above - Write your answer with 4 significant
figures:
Your Answer =
8)Calculate the number of atoms per cubic meter in Metal B (units
atoms/m3). Write your answer with 4 significant figures
:
Your Answer =
9) What is the composition, in atom percent, of an alloy that
contains a) 36 g Metal A and b) 47 g Metal B? Composition for Metal
A (%):
Your Answer =
10) What is the composition, in atom percent, of an alloy that
contains a) 36 g Metal A and b) 47 g Metal B? Composition for Metal
B (%):
Your Answer =
11) What is the composition of Metal A in atom percent, if the
alloy consists of 4.5 wt% Metal A and 95.5 wt% of Metal
B?
Your Answer =
12) What is the composition of Metal B in atom percent, if the
alloy consists of 4.5 wt% Metal A and 95.5 wt% of Metal
B?
Your Answer =
Releation between edge length and radius of atom for FCC = a = r√8
a = edge length
r = radius of atom
a = 0.116 nm x √8
volume = a3 = (0.116 nm x √8 )3 = 0.03532 nm3 = 3.53 x 10-2 nm3
2.
atomic packing factor = volume of atoms in unit cell / total voulme of unit cell
relation between edge length and radius for BCC = a = 4r/√3
volume of unit cell = (4r/√3)3
total no. of atoms in BCC inside unit cell = 2
volume of atoms inside unit cell = 2 x 4/3 x pi x r3
atomic packing factor = 2 x 4/3 x pi x r3 / (4r/√3)3 = 0.6798 ~ = 0.68
3.
theoretical density = mass of atoms inside cell / volume of unit cell
in FCC there are 4 atoms inside unit cell = 4 x 197g / 6.022 x 1023 = 130.85 x 10-23 g
volume calculated in part 1 = 3.53 x 10-2 nm3 = 3.53 x 10-2 x 10-21 cm3
density = mass / volume = 130.85 x 10-23 g / 3.53 x 10-2 x 10-21 cm3 = 37.06899 g/cm3
please ask rest of them seperately thanks!
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