Question

At what pressure is liquid n-hexane in equilibrium with its vapour at 450K?

At what pressure is liquid n-hexane in equilibrium with its vapour at 450K?

Homework Answers

Answer #1

the pressure we have to find is the vapor pressure at 450K.

Vapor Pressure of a liquid is defined as the equilibrium pressure exerted by vapor with the liquid at the given temperature.

Here we have n-hexane at 450K.

This can be estimated with the use of Antoine equation.

Psat is in torr or mmHg

T is in oC = 450-273.15=176.85oC

Antoine constants for n-hexane for given temperature.

A=7.01051

B=1246.33

C=232.988

Solving gives,

760mmHg = 1 atm = 101325 Pa

Thus our answer is 1242.75 kPa.

Hope this is clear for you.

feel free to ask if having any doubts.

Rate/Feedback is really appreciated.

Know the answer?
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for?
Ask your own homework help question
Similar Questions
Pentane and hexane form an ideal solution. At 25degrees the vapour pressure of pentane and hexane...
Pentane and hexane form an ideal solution. At 25degrees the vapour pressure of pentane and hexane are 511 and 150.0 torr, respectively. A solution is prepared by mixing 25ml pentane (density, 0.63g/ml) with 45 ml hexane (density, 0.66g/ml) a) What is the vapour pressure of the resulting solution b) What is the composition by mole fraction of pentane in the resulting vapour that is in equilibrium with this solution? c) Is it reasonable to assume that this is an ideal...
A binary liquid mixture of benzene and toluene is in equilibrium with its vapour at a...
A binary liquid mixture of benzene and toluene is in equilibrium with its vapour at a pressure of 1.5 atm. The liquid mole fractions of benzene and toluene are equal. Show that vapour-liquid equilibrium occurs at a temperature of 379.6 K and calculate the corresponding mole fractions of benzene and toluene in the vapour phase. You may assume ideal solution behaviour. Antoine’s coefficients for toluene: A = 16.014 , B = 3094.5 , C = -53.75 Antoine’s coefficients for benzene:...
At 35°C a liquid solution containing 40.5 mol % ethanol and 59.5 mol % methylcyclo-hexane exerts...
At 35°C a liquid solution containing 40.5 mol % ethanol and 59.5 mol % methylcyclo-hexane exerts a pressure of 152.4 mmHg. The vapour phase composition is 54.7 mol % ethanol and 45.3 mol % methylcyclo-hexane. The vapour pressures of the pure compounds at 35°C are 103.1 mmHg and 73.6 mmHg for ethanol and methylcyclo-hexane respectively. Using Van Laar model, estimate the mol fraction of ethanol in the vapour phase in equilibrium with a liquid phase containing 60 mol % ethanol...
Choose a liquid, find its vapour pressure at room temperature from literature and its standard boiling...
Choose a liquid, find its vapour pressure at room temperature from literature and its standard boiling temperature to calculate its enthalpy of vaporization.  
Evaporation and Vapour Pressure You perform a procedure with liquid X and liquid Y. Liquid X...
Evaporation and Vapour Pressure You perform a procedure with liquid X and liquid Y. Liquid X undergoes a temperature change of 10°C and liquid Y undergoes a temperature change of 15°C. Which of the two liquids has stronger intermolecular forces? Explain.
If the reference state of n-hexane is set as liquid at 25 °C and 1 bar,...
If the reference state of n-hexane is set as liquid at 25 °C and 1 bar, what is the enthalpy of the n-hexane at the exit condition in problem 3? What is the enthalpy of n-hexane as a vapor at 85 °C? For n-hexane as a liquid: Cp(J/mol K) =–75.225 + 1.176 T–1.344 x 10-3 T^2
The equilibrium vapour pressures of ethanol and chloroform at 45oC are 230.33 mbar and 578.0 mbar...
The equilibrium vapour pressures of ethanol and chloroform at 45oC are 230.33 mbar and 578.0 mbar respectively. The Henry’s law constants for ethanol at 45oC is 1030.3 mbar. A non‐ideal solution of the two liquids has a mole fraction of ethanol in the liquid phase of 0.115.  The equilibrium vapour pressure of chloroform above the solution is 533.7 mbar and the equilibrium vapor pressure of the ethanol is 73.95 bar. (a) Find the mole fraction of ethanol in the vapour phase...
Consider a mixture of 30% n-butane, 35% n-hexane, 35% n-heptane. If the pressure is 202 kPa,...
Consider a mixture of 30% n-butane, 35% n-hexane, 35% n-heptane. If the pressure is 202 kPa, calculate the dew point temperature in ?C and the unknown mole fractions. Specify whether the unknown mole fractions are vapor or liquid.
A mixture of n-heptane and n-hexane containing 25 mol% n-hexane is vaporized at a pressure of...
A mixture of n-heptane and n-hexane containing 25 mol% n-hexane is vaporized at a pressure of 100kPa. Determine the following a)The bubble point temperature b)The composition of the vapor The vapor pressures are given by the Antoine equation: lnP*= A-(B/T-C) Where P is in kPa and T is in K. The Antoine constants are given as follows: n-heptane: A=13.8587,B=2911.32,C=56.51 n-hexane: A=13.8216,B=2697.55,C=48.78
a mixture of 65 mol % n hexane and 35 mole % n octane is fed...
a mixture of 65 mol % n hexane and 35 mole % n octane is fed to a flash drum operating at 1500 mm Hg. Feed rate is 100 gmol/s. Mixture is heated to 110 degrees celcius, which the mixture vaporizes. Vapor and liquid products are removed constantly, A) Calculatae the vapor and liquid product compositions (Mol % n hexane and n octane) B) Calculate the vapor and liquid flow rates (gmol/s) y hex = 0.7 x hex = 0.6...
ADVERTISEMENT
Need Online Homework Help?

Get Answers For Free
Most questions answered within 1 hours.

Ask a Question
ADVERTISEMENT