Part A
For the reaction
2CH4(g)?C2H2(g)+3H2(g)
K = 0.150 at 1704 ?C . What is Kp for the reaction at this temperature?
Express your answer numerically.
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Kp = |
Part B
For the reaction
N2(g)+3H2(g)?2NH3(g)
Kp = 5.10×10?3 at 251 ?C . What is K for the reaction at this temperature?
Enter your answer numerically.
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K = |
Part a
2CH4(g)?C2H2(g)+3H2(g)
n = sum of stoichiometric coefficient of products - sum of stoichiometric coefficient of reactants
= (3 + 1) - 2 = 2
Gas constant R = 0.0821 L-atm/mol·K
Temperature T = 1704 + 273 = 1977 K
Relation between Kc and Kp
Kp = Kc (RT)n
= 0.150 x (0.0821 x 1977)2
= 3.95 x 10^3
Part b
N2(g)+3H2(g)?2NH3(g)
n = sum of stoichiometric coefficient of products - sum of stoichiometric coefficient of reactants
= (2) - (1+3) = - 2
Gas constant R = 0.0821 L-atm/mol·K
Temperature T = 251 + 273 = 524 K
Relation between Kc and Kp
Kp = Kc (RT)n
5.10 x 10^-3 = Kc x (0.0821 x 524)-2
Kc = 9.44
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