Calculate the theoretical density of silicon of given that the Si-Si bond distance is 0.235 nm. Give your results in megagrams per metter cubed (Mg/m^3).
Si-Si bond distance
d = 0.235 nm
nearest neighbor to atom = 0.25 of body diagonal
body diagonal of cube = ?3 a
d = ?3 a/4
0.235 = ?3 a/4
a = 0.235*4/?3
= 0.543 nm
Volume = 0.543^3 = 0.160103007 nm3 x (1m/10^9nm)3
= 1.601 x 10^-28 m3
Number of atoms in cubic unit cell
Nu = 8×1/8 + 6 ×1/2 + 4
= 8
Molar mass of Si = 28.085 amu
1amu = 1.660 ×10^?27 kg
Total mass = 8 x 28.085 x 1.660 ×10^?27 kg
= 3.729 x 10^-25 kg
Density = mass/volume
= 3.729 x 10^-25 kg / 1.601 x 10^-28 m3
= 2329.1255 kg/m3 x 0.001 Mg/kg
= 2.329 Mg/m3
Get Answers For Free
Most questions answered within 1 hours.