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The equations that connect the wavenumbers of rotational transitions with rotational and centrifugal distortion constants can...

The equations that connect the wavenumbers of rotational transitions with rotational and centrifugal distortion constants can be arranged as:

v(J+1 <- J) /{2(J+1)}=B-2DJ(J+1)2

which is the equation of a straight line when the left-hand side is plotted against (J+1)2. The following wavenumbers of transitions (in cm-1) were observed for 16C18O:

J 0 1 2 3 4
3.845033 7.689919 11.534510 15.378662 19.22223

Determine B, DJ, and the equilibirum bond length of CO.

Engineering   Chemical-Engineering   
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