(a) From the data, plot the enthalpy of 1 mole of solution at 27ᵒC as a function of the weight percent HNO3. Use as reference states liquid water at 0ᵒC and liquid HNO3 at 0ᵒC. You can assume that Cp for H2O is 75 J/g mol .ᵒC and for HNO3, 125 J/g mol.ᵒC.
-ΔHsoln at 27ᵒC (J/g mol HNO3) | Moles H2O added To 1 mole HNO3 |
0 | 0.0 |
3350 | 0.1 |
5440 | 0.2 |
6900 | 0.3 |
8370 | 0.5 |
10880 | 0.67 |
14230 | 1.0 |
17150 | 1.5 |
20290 | 2.0 |
24060 | 3.0 |
25940 | 4.0 |
27820 | 5.0 |
30540 | 10.0 |
31170 | 20.0 |
b) Compute the energy absorbed or evolved at 27ᵒC on making a solution of 4 moles of HNO3, and 4 moles of water by mixing a solution of 33 1/3 mol % acid with one of 60 mol % HNO3.
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