An iron-carbon alloy initially containing 0.219 wt% C is exposed to an oxygen-rich and virtually carbon-free atmosphere at 1190°C. Under these circumstances the carbon diffuses from the alloy and reacts at the surface with the oxygen in the atmosphere; that is, the carbon concentration at the surface position is maintained essentially at 0.0 wt% C. At what position will the carbon concentration be 0.164 wt% after a 8 h treatment? The value of D at 1190°C is 1.6 × 10-10 m2/s.
Equation. : C (x,t)- Co/Cs-Co = 1-erf(x/2)
t = 8 hrs = 8 x 3600 secs = 28800 secs
Co = 0.219 wt%
Cx,t = 0.164 wt%
Cs = 0 %
Insert these values in the above equation ,
0.164 -0.219/0-0.219 = 1-erf (x/2Dt)
0.2511 = 1-erf (x/2Dt)
0.2511-1 = -erf (x/2Dt)
0.7488 = erf (x/2Dt)
Based on z value table and linear interpolation
Z. erf (z)
0.8 . 0.7421
Z. 0.7488
0.85. 0.7707
Z-0.8/0.85-0.8 = 0.7488-0.7421/0.7707-0.7421
Z-0.8/0.05 = 0.0067/0.0286
Z-0.8 = 0.0117
Z = 0.0117+0.8 = 0.8117
This shows that . X/2Dt = 0.8117
X = 0.8117 x 2 1.6 ×10-10 m2/s×28800 s
X = 0.8117 x 2 x 214.66 x 10-5 m
x = 348.48 x 10-5 m = 3.48 mm
The x value = 3.48 mm
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