A 2.93-g sample of an alkaline earth metal chloride is trated
with excess silver nitrate. All of the chloride is recovered as
7.57 g of silver chloride. What is the name of the
alkaline earth metal?
Mass of alkaline earth metal = 2.93 g
Mass of AgCl = 7.57 g
Moles of AgCl = mass/molecular weight
= (7.57 g) / (143.32 g/mol)
= 0.052819 mol
Assume any alkaline earth metal = XCl2
Silver nitrate = AgNO3
The balanced reaction
XCl2 + 2AgNO3 = X(NO3)2 + 2AgCl
Excess reactant = AgNO3
Limiting reactant = XCl2
From the stoichiometry of the reaction
2 mol AgCl produced from = 1 mol XCl2
0.052819 mol AgCl produced from = 0.052819/2
= 0.026409 mol XCl2
Molecular weight of XCl2 = mass/moles
= 2.93 g / 0.026409 mol
= 110.95 g/mol
Molecular weight of XCl2 = molecular weight of X + 2*Molecular weight of Cl
110.95 = X + 2*35.5
X = 39.95 g/mol
X = calcium (Ca)
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