The space shuttle environmental control system handled excess CO2 (which the astronauts breathe out; it is 4.0% by mass of exhaled air) by reacting it with lithium hydroxide, LiOH, pellets to form lithium carbonate, Li2CO3, and water. If there were seven astronauts on board the shuttle, and each exhales 20. L of air per minute, how long could clean air be generated if there were 25,000 g of LiOH pellets available for each shuttle mission? Assume the density of air is 0.0010 g/mL
LiOH + CO2 = Li2CO3 + H2O
balance
2LiOH + CO2 = Li2CO3 + H2O
n = 7 astronauts
V = 20 L per min each
find total time for
m = 25000 g to last
First,
find moles of CO2 present:
mol of CO2 = from % of air
mass of air -->volume of air
Volume of air --> 20 L per astronaut--> 7*20 = 140 L per minute
of which
mass = D*V = 140000 * 0.0010 = 140 g of ai
4% is CO2 so --> 4/100*140 = 5.6 g of CO2 per min
mol of CO2 = mass/MW = 5.6/44 = 0.12727 mol of CO2 per min
mol of LiOH present --> mass/MW = 25000/23.95 = 1043.841 mol of LiOH
now...
2 mol of LiOH = 1 mol of CO2
1043.841 /2 = 521.92 mol of CO2
the rate
0.12727 mol of CO2 per min
time = 521.92 /0.12727 = 4100.88 mins --> 4100.88/60 = 68.34 hours --> 2.85 days
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