If He(g) has an average kinetic energy of 6750 J/mol under certain conditions, what is the root mean square speed of O2(g) molecules under the same conditions?
He:
KE_ave = ½ M( Vrms)²
Vrms = [2 KE_ave / M]1/2
M = molar mass of He = 4 x 10-3 kg/mol
Given that average kinetic energy KE_ave = 6750 J/mol
Hence,
Vrms = [2 KE_ave / M]1/2
= [2 x 6750 J/mol / 4 x 10-3 kg/mol]1/2
= 1837.1 m/s
Vrms = 1837.1 m/s
Therefore,
root mean square speed of He = 1837.1 m/s
O2:
Vrms = [3 RT / M]1/2
Vrms (O2) /Vrms (He) = [MHe/ MO2]1/2
Vrms (O2) = Vrms (He) x [MHe/ MO2]1/2
= (1837.1 m/s) x [4 x 10-3 / 32 x 10-3]1/2
= 649.5 m/s
Vrms (O2) = 649.5 m/s
Therefore, root mean square speed of O2(g) molecules = 649.5 m/s
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