Question

Calculate the zero point energies for 1H19F and 2D19F. Compare the difference in the zero point...

Calculate the zero point energies for 1H19F and 2D19F. Compare the difference in the zero point energies to kBT at 298 K.

Homework Answers

Answer #1

Force constant of 1H19F = 970 N/m

Frequency, v = 1/2

=  1/2[ 970 / (1.008 amu * 18.998 amu / 1.008 + 18.998) * 1.661x10^-27 kg/amu ]

= 1/2[ 970 / (19.149984 / 20.006) * 1.661x10^-27 kg ]

= 1/2[ 970 / (1.5899x10^-27 kg ]

= 1.243x10^14 s-1

Zero point energy of 1H19F,

Eo = hv / 2 = 6.626x10^-34 * 1.243x10^14 / 2

Eo = 4.11x10^-20 J

For 2D19F -

Frequency, v = 1/2

=  1/2[ 970 / (2.0140 amu * 18.998 amu / 2.0140 + 18.998) * 1.661x10^-27 kg/amu ]

= 1/2[ 970 / (38.2619 / 21.012) * 1.661x10^-27 kg ]

= 1/2[ 970 / (3.0246x10^-27 kg ]

= 9.013x10^13 s-1

Zero point energy of 2D19F,

Eo = hv / 2 = 6.626x10^-34 * 9.013x10^13 / 2

Eo = 2.98x10^-20 J

Difference in zero point energies to kBT at 298 K -

EoHF - EoDF / kT = (4.11x10^-20 - 2.98x10^-20) / 298 * 1.38x10^-23

= 2.747

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