Question

Using the highest value of lead from the first draw data set, and assuming a resident...

Using the highest value of lead from the first draw data set, and assuming a resident drinks 3.5 L of water per day, calculate the mass of lead that the resident would consume over the course of one year. (Assume the water has a density of 1.0 g/mL) Express your answer to two significant figures.

First, calculate the mass of water consumed in one year. Then, use the highest lead level in the first-draw method's data set to calculate the mass of lead found in that mass of water. The assumed density of water, 1.0 g/mL , can also be written as 1000 g/L . The unit ppb is equivalent to (g solute)/(109 g solvent)(g solute)/(109 g solvent).

Sample number

Lead level
first draw
(
ppbppb)

Lead level
45-
ssflush
(
ppbppb)

Lead level
2-
minminflush
(
ppbppb)

1

0.344

0.226

0.145

2

8.133

10.77

2.761

3

1.111

0.11

0.123

4

8.007

7.446

3.384

5

1.951

0.048

0.035

6

7.2

1.4

0.2

7

40.63

9.726

6.132

8

1.1

2.5

0.1

9

10.6

1.038

1.294

10

6.2

4.2

2.3

11

4.358

0.822

0.147

12

24.37

8.796

4.347

13

6.609

5.752

1.433

14

4.062

1.099

1.085

15

29.59

3.258

1.843

Source: FlintWaterStudy.org (2015) "Lead Results from Tap Water Sampling in Flint, Michigan, during the Flint Water Crisis"

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Homework Answers

Answer #1

Lets assume the resident drinks 3.5 L of water per day

Then in 1 yr = 365 days, total water consumed by her = 3.5 * 365 = 1,277.5‬ L

Then mass of water consumed in 1 yr = density * volume

= 1.0 g/mL * 1,277.5‬ L

= 1Kg / L * 1,277.5‬ L

= 1,277.5 Kg

Now in the first draw data set, the highest amount of lead sample (7) = 40.63 ppb

We know ppb = mass of solute in gram / mass of solvent in 109 gram

i.e mass of solute (lead) present per 109 gram of solvent (water)

Here 40.63 ppb of lead means 40.63 g of lead is present in 109 gram water

Or we can say, in 109 gram = 106 Kg of water, we have lead = 40.63 g

Then in 1,277.5 Kg of water, we have lead = 40.63 g/ 106 Kg * 1,277.5 Kg

= 0.0519 g

= 5.2 * 10-2 g

i.e mass of lead that the resident would consume over the course of one year = 5.2 * 10-2 g

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